Electroluminescent
inorganic materials are well known since several years
and inorganic based light emitting diodes (LED) have
been commercially available since the early '60s.
Electroluminescence from organic materials has been
discovered in the same period, but the operating conditions
required for many commercial applications and for the
development of Organic Light Emitting Diodes
(OLED)s and Polymer Light Emitting
Diodes (PLED)s have been reached only in the
'80s.
Monochromatic screens based on these organic devices
have been introduced on the market in 1997.
In an organic light emitting diode, a thin layer of
organic material is cast between two electrodes and
one of them has to be semitransparent to permit the
visible output of light.
A highly conjugated polymer is layered as thin film
on the top of ITO (Indium Tin Oxide) a semi-transparent,
semiconducting material that behave as the anode.
On the top of the polymeric layer is evaporated under
high vacuum a metallic contact, which works as the cathode.
When an external voltage is applied to the electrodes,
transport carriers with opposite charges (electrons
and holes) are injected in the organic emissive layer
and move into it under the action of the external applied
electric field (>105 V/cm).
The further recombination of electron and holes within
the bulk of the polymer permits the emission of light.
Centro Laser has reached a good level of knowledge in
the fabrication of those devices.
Sputtering ITO deposition, casting of organic materials
via spin coating or thermal evaporation (for insoluble
polymers) and deposition of metallic contacts have been
diffusely investigated.
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OLED layout and operation mode

Example of OLED |